WLN-CA.W.27.2Determination of iodate, chlorite and bromate by means of ion chromatographyin-house method
Principle:Iodate, chlorite and bromate are separated on a column filled witha low capacity ion exchanger consisting of inert cores of styrene /divinylbenzene copolymer to which tetramethyl ammonium groups have been applied. A sodium carbonate / sodium hydrogencarbonate solutionis used as eluent. The separated ions are detected by measuring thespecific (electric) conductance of the liquid flow. By placing a membrane suppressor after the separation column, the cations in the sample and the sodium ions from the eluent are exchanged for the hydronium ions (H3O +). As a result, the specific conductivity of the eluent liquid is greatly reduced by the formation of H2CO3. Also, due to the higher specific conductivity of the hydrogen ion, a significantly higher sensitivity is obtained with respect to the remaining cations.
Determination:Bromate
Performance characteristics:
Matrices qualified by the Dutch RvA:Drinking water, Groundwater, Surface water
Reporting limit:0.5 μg/l, matrix dependent
Measurement uncertainty:40%
Sustainability:28 days , if conserved with Ethylenediamine
Sampling bottle:Plastic , white , 125 ml , conservation with Ethylenediamine
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[ 28-11-2024 23:15:44 ]